Bis{2-[(E)-benzyliminomethyl]-4-methylphenolato-κ2 N,O}nickel(II)
نویسندگان
چکیده
In the title complex, [Ni(C(15)H(14)NO)(2)], the Ni(II) atom is located on an inversion centre and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a slightly distorted square-planar geometry. The phenyl and benzene rings in the ligand mol-ecule form a dihedral angle of 72.79 (8)°.
منابع مشابه
Bis[2-(benzyliminomethyl)-4-chlorophenolato-κ2 N,O]nickel(II)
In the mononuclear centrosymmetric title compound, [Ni(C(14)H(11)ClNO)(2)], the Ni(II) atom, lying on a center of symmetry, is four-coordinated by two O atoms and two N atoms from two Schiff base ligands, forming a slightly distorted square-planar environment. The dihedral angle between the two aromatic rings of the ligand is 72.0 (2)°. No significant hydrogen bonding or π-π stacking inter-acti...
متن کاملBis{2-[(E)-benzyliminomethyl]-4-methylphenolato-κ2 N,O}cobalt(II)
In the title complex, [Co(C(15)H(14)NO)(2)], the Co(II) atom, situated on an inversion centre, is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a slightly distorted square-planar geometry. The two phenolate rings form a dihedral angle of 10.53 (2)°.
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متن کاملcatena-Poly[[bis(O,O′-diisopropyl dithiophosphato-κ2 S,S′)nickel(II)]-μ-bis(4-pyridylmethylene)diazane-κ2 N:N′]
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In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolate ligands, displaying a distorted tetra-hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol-ecular symmetry of the complex is C(2). The two phenolate rings are perpendicular...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009